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51.
52.
《Ceramics International》2022,48(8):10601-10612
Using MgC2O4, Mg powders as raw materials and Ni(NO3)2?6H2O as a catalyst, CNTs/MgO composite powders were prepared by a catalytic combustion synthesis method. The CNTs/MgO composite powders were characterized by XRD, Raman spectroscopy, FESEM/EDS and HRTEM. The effects of catalyst content on the degree of graphitization and aspect ratio of the CNTs in composite powders were investigated. Moreover, the thermal shock resistance of low-carbon Al2O3–C refractories after adding the composite powder was investigated. The results indicated that the CNTs prepared with 1 wt% Ni(NO3)2?6H2O addition had a higher degree of graphitization and aspect ratio. In particular, the aspect ratio could reach approximately 200. The growth mechanism of hollow bamboo-like CNTs in the composite powders was proven to be a V-L-S mechanism. The thermal shock resistance of Al2O3–C samples could be improved significantly after adding CNTs/MgO composite powders. In particular, compared with CM0, the residual strength ratio of Al2O3–C samples with added 2.5 wt% composite powders could be increased 63.9%. 相似文献
53.
Poly(4-styrenesulfonic acid) (PSSA) doped polypyrrole (PPy)/tungsten oxide (WO3)/reduced graphene oxide (rGO) hybrid nanocomposite have been successfully synthesized using appropriate amounts of PSSA, pyrrole monomer, WO3, and rGO dispersed in aqueous solution through in situ chemical oxidation polymerization. Here, a simple spin coating method was used to fabricate a nitric oxide (NO) gas sensor composed of the aforementioned nanocomposite on a surface acoustic wave (SAW) resonator. This sensor can detect NO gas at concentrations of 1–110 parts per billion (ppb) at room temperature in dry air, with a sensitivity of 12 Hz/ppb and response and recovery times of <2 min. Moreover, its limit of detection (LOD) is 0.31 ppb for a signal to noise ratio of 3. It demonstrates repeatability, fast response, and recovery at room temperature. Moreover, its sensory performance remains highly stable over 30 days with only a 6.3% decrease in sensitivity. In addition, the sensor is highly selective for NO, even when nitrogen dioxide, ammonia, and carbon dioxide are applied as interfering gases. The inclusion of rGO (with large specific surface area) and the synergic effect of n-type WO3 nanoparticles in the p-type PPy matrix (leading to p-n heterojunction region formation) possibly underlie the efficient sensing performance of our sensor. 相似文献
54.
Impact of preheating on the mechanical performance of different MgO–C bricks - Low temperature range
《Ceramics International》2021,47(24):34869-34880
This work complements an initial study regarding the mechanical behavior of MgO–C bricks at 1000 °C. In this case, two bricks bonded with phenolic resin, one of them containing aluminum, were treated at 600 °C and mechanically tested at RT and 600 °C. The thermal treatments attempt to simulate the in-service steelmaking ladle preheating process. At low temperatures, the binder pyrolysis is one of the main transformations and the Al melting neither its chemical reactions occur on a large scale yet. To evaluate the effects as the pyrolysis progresses, the soaking time at 600 °C was varied from 1 to 3 h. Although without significant chemical activity, the presence of Al affected the mechanical behavior of the tested bricks. The consolidation of the C–C network coming from the binder pyrolysis was identified as the main factor responsible for counterbalancing the material's degradation by microcracking. The heating combined with the low compressive pre-load applied on the tested specimens appears to close the microcracks and pores. 相似文献
55.
Zhenkun Ke Xin Cao Chuanli Shan Lifen Shi Pingping Wang Yong Yang Fengyang Zhao Jiedong Cui Jinwei Li Gang Zhou Min Guan Tao Yu 《Ceramics International》2021,47(14):19605-19613
The purpose of the current work was to research the effect of alkali metal oxide on the structure, thermal properties, viscosity and chemical stability in the glass system (R2O–CaO–B2O3–SiO2) systematically. Because the glass would emulsify when Li2O was added to the glass batch, this article did not discuss Li2O. The results showed that when the amount of Na2O was less than 4 mol.%, there was a higher interconnectivity of borate and silicate sub-networks in glass, as more mixed Si–O–B bonds were present in glass. The glass samples exhibited excellent thermal properties and chemical stabilities. As the amount of Na2O exceeded 4 mol.%, the interconnectivity of borate and silicate sub-networks was weakened. The thermal properties and chemical stabilities of the glass samples were reduced. The connectivity of the silicate sub-network was weakened slightly as the Na/K ratio varied, and the coefficient of thermal expansion (CTE) of the glass samples gradually increased, and the resistance to thermal shock (RTS) value gradually decreased. Moreover, the viscosity of the glass samples decreased with the ratio of Na/Si and Na/K increased. 相似文献
56.
Although tremendous efforts have been made to ensure fresh produce safety, various foodborne outbreaks and recalls occur annually. Most of the current intervention strategies are evaluated within a short timeframe (less than 1 h), leaving the behavior of the remaining pathogens unknown during subsequent storages. This review summarized outbreak and recall surveillance data from 2009 to 2018 obtained from government agencies in the United States to identify major safety concerns associated with fresh produce, discussed the postharvest handling of fresh produce and the limitations of current antimicrobial interventions, and reviewed the intervention strategies that have the potential to be applied in each storage stage at the commercial scale. One long-term (up to 12 months) prepacking storage (apples, pears, citrus among others) and three short-term (up to 3 months) postpacking storages were identified. During the prepacking storage, continuous application of gaseous ozone at low doses (≤1 ppm) is a feasible option. Proper concentration, adequate circulation, as well as excess gas destruction and ventilation systems are essential to commercial application. At the postpacking storage stages, continuous inhibition can be achieved through controlled release of gaseous chlorine dioxide in packaging, antimicrobial edible coatings, and biocontrol agents. During commercialization, factors that need to be taken into consideration include physicochemical properties of antimicrobials, impacts on fresh produce quality and sensory attributes, recontamination and cross-contamination, cost, and feasibility of large-scale production. To improve fresh produce safety and quality during storage, the collaboration between researchers and the fresh produce industry needs to be improved. 相似文献
57.
《International Journal of Hydrogen Energy》2021,46(64):32665-32675
The thermal management of a proton exchange membrane fuel cell (PEMFC) is crucial for fuel cell vehicles. This paper presents a new simulation model for the water-cooled PEMFC stacks for automotive vehicles and cooling systems. The cooling system model considers both the cooling of the stack and cooling of the compressed air through the intercooler. Theoretical analysis was carried out to calculate the heat dissipation requirements for the cooling system. The case study results show that more than 99.0% of heat dissipation requirement is for thermal management of the PEMFC stack; more than 98.5% of cooling water will be distributed to the stack cooling loop. It is also demonstrated that controlling cooling water flow rate and stack inlet cooling water temperature could effectively satisfy thermal management constraints. These thermal management constraints are differences in stack inlet and outlet cooling water temperature, stack temperature, fan power consumption, and pump power consumption. 相似文献
58.
《Ceramics International》2022,48(2):1814-1819
Sr3Al2-xBxO5Cl2:Eu2+, Dy3+ (x = 0, 0.2, 0.4) long persistent phosphors were prepared via solid-state process. The pristine Sr3Al2O5Cl2:Eu2+, Dy3+ phosphor exhibits orange/red broad band emission around 609 nm, which can be attributed to the electric radiation transitions 4f65 d1→4f7 of Eu2+. Upon the same excitation, the B3+-doped Sr3Al2-xBxO5Cl2:Eu2+, Dy3+ phosphors display red-shift from 609 nm to 625 nm with increasing B3+ concentrations. The XRD patterns show that Al3+ can be replaced by B3+ in the host lattice at the tetrahedral site, which causes lattice contraction and crystal field enhancement, and thereafter achieves the red-shift on the emission spectrum. The XPS investigation provides direct evidence of the dominant 2-valent europium in the phosphor, which can be ascribed for the broad band emission of the prepared phosphors. The afterglow of all phosphors show standard double exponential decay behavior, and the afterglow of Sr3Al2O5Cl2:Eu2+, Dy3+is rather weak, while the sample co-doped with B3+shows longer and stronger afterglow, as confirmed after the curve simulation. The analysis of thermally stimulated luminescence showed that, when B3+ is introduced, a much deeper trap is created, and the density of the electron trap is also significantly increased. As a result, B3+ ions caused redshift and enhanced afterglow for the Sr3Al2-xBxO5Cl2:Eu2+, Dy3+ phosphor. 相似文献
59.
《Ceramics International》2022,48(5):6124-6130
The behaviour of the promising glass sealant 54.4SiO2-13.7Na2O-1.7K2O-5.0CaO-12.4MgO-0.6Y2O3-11.3Al2O3-0.9B2O3 for solid oxide fuel cells (SOFCs) under SOFC operating conditions was studied. First, the kinetics of the crystallisation processes at the operating temperature (850 °C) was discussed (maximum exposure time of 1000 h), and the effect of crystallisation on the coefficient of thermal expansion (CTE) of the sealant was studied. Furthermore, the degradation processes at the interface of the glass sealant and functional SOFC materials (Crofer 22 APU, YSZ, and NiO(Ni)-YSZ) during exposure to 850 °C in oxidising and reducing atmospheres for 500 h were studied. The tests demonstrated good performance of the sealant studied and possibility of its application in SOFCs. 相似文献
60.
《Ceramics International》2022,48(5):6208-6217
Three different coatings, namely TiAlN, TiAlN (external)/NbN (internal) and NbN (external)/TiAlN (internal), were deposited on cemented carbides by arc ion plating. The comparative investigation conducted in this study elucidates the effect of the NbN layer and coating systems on the growth, mechanical properties, and tribological performance of the coatings. The results showed that the surface of the TiAlN and TiAlN/NbN coatings was smoother when TiAlN served as the external layer. The NbN/TiAlN coating, wherein NbN formed the external layer, had a much rougher but more symmetrical surface. With the introduction of the NbN layer, the increased micro stress induced a lower adhesion strength in the TiAlN/NbN and NbN/TiAlN coatings. The TiAlN/NbN and NbN/TiAlN coatings exhibited higher hardness and hardness/effective elastic modulus (H/E*). During the friction test, when the temperature was elevated to 700 °C, the tribological performance of the monolayer TiAlN coating was the lowest because of the TiO2-induced breakage of the dense tribo-oxide film. The NbN layer participated in the formation of a NbOx film at elevated temperatures, which was responsible for the high tribological performance of the two bilayer coatings. When the NbN layer was on the outermost layer and in direct contact with the elevated temperature atmosphere, the NbN/TiAlN coating generated a tribo-oxide film with high integrity, and its coefficient of friction decreased by 27% of that at room temperature. Therefore, the NbN/TiAlN coating exhibited the highest wear resistance at 700 °C. 相似文献